Uranium-mediated activation of small molecules.
نویسنده
چکیده
Molecular complexes of uranium are capable of activating a range of industrially and economically important small molecules such as CO, CO(2), and N(2); new and often unexpected reactions provide insight into an element that needs to be well-understood if future clean-energy solutions are to involve nuclear power.
منابع مشابه
Small molecule activation at uranium coordination complexes: control of reactivity via molecular architecture.
Electron-rich uranium coordination complexes display a pronounced reactivity toward small molecules. In this Feature article, the exciting chemistry of trivalent uranium ions coordinated to classic Werner-type ligand environments is reviewed. Three fundamentally important reactions of the [(((R)ArO)3tacn)U]-system are presented that result in alkane coordination, CO/CO2 activation, and nitrogen...
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ورودعنوان ژورنال:
- Chemical communications
دوره 47 32 شماره
صفحات -
تاریخ انتشار 2011